Galip Sarper Koçlar’s master’s thesis #paper on #gelcasting of #alumina #ceramics #materials with #gelatin and #carrageenan gum. He got best results with 5% by weight gelatin, or 1.7% by weight carrageenan, which resulted in significantly lower fired hardness but higher fired compressive strength than the gelatin, and all his trials were with 47–53% alumina, which reached 95.8% after firing at 1550°, and a bit of Dolapix dispersant. 17.5% linear shrinkage. In English, not Turkish, although it’s kind of broken English. The introduction has the best #survey of gelcasting I’ve found so far. Apparently #acrylamide (and, I guess, other similar binders) needs 30–60 minutes to gel in the mold. He also mentions existing “natural gelcasting” processes for technical ceramics using “starch, ovalbumin, chitosan, alginades [sic; should be #alginate], #gelatin, carragenan [sic] gum and [sic] etc.”, and agarose, with the disadvantage being lower green strength.
on 02015-08-15Turns out #acrylamide is a (potential) human carcinogen, and the acute fatal dose is a few grams. However, polyacrylamide, a highly water-absorbent plastic, is so nontoxic it’s used in contact lenses and as a subdermal filler. #toxicology
on 02015-08-15ORNL developed #gelcasting for “technical” #ceramics #materials (including #silicon-nitride) in the 1980s and 1990s, and this is a #popsci overview; apparently Mark Janney, Stephen Nunn, Claudia Walls, and Ogbemi Omatete are recognized as the inventors. Apparently the advantage over slipcasting is that shrinkage is uniform and the green casting is strong enough to be machinable. Initial experiments used methylcellulose, which gels when heated with water, as the gelifying binder, but “multifunctional acrylate” polymers (??) were the binder that made gelcasting practical, followed by water-based #acrylamide, then less-toxic methacrylamide.
on 02015-08-15